I have checked with our CRT expert and he thinks that any 'normal' type of scratch does not pose any danger. Usual disclaimer applies ... (what is 'normal'?)
The front of the tube is much thicker and stronger than the rear. It has to be, to withstand the air pressure, because the curvature radius is so much larger. You won't break it by throwing a slipper at it. The neck is in fact very easy to break, usually without causing injuries to anyone.
Normally, if the tube should implode, the rimband (the tensioned steel band around the rim of all modern CRTs of any size) prevents the glass from flying outward too far. Every tube type has to pass tests in which it is deliberately imploded and it is checked whether any large shrapnel flies too far out.
What *is* very dangerous is a CRT with its rimband missing, or a CRT which never had a decent rimband in the first place (like some dubious Russian-made samples we once saw). Such a tube should not be handled at all. NEVER ever attempt to remove the rimband for and reason!
I just saw a picture tube that was broken due to dropping the (entire) TV on one corner. In the cone (the backside) there are open cracks of some 3 feet length in total. Nevertheless all the glass is still in its original place and it looks as if no glass has flown outward. The faceplate is still intact. So in this case nobody would have got hurt. I remember reading about Americans (who else?) who tried to shoot CRT's with smaller rifles, with little or no success.
Does this comfort you? Get out the shotgun and have a go at it!
so 100+ years sounds good to me if you need a time